INORGANIC CHEMISTRY
Principles of structure And Reactivity
FOURTH EDITION
By-James E. Huheey Ellen A. Keiter Richard L. Keiter
University of Maryland Eastern Illinois University Eastern Illinois University
The content given in the book will be invaluable to teaching and learning concept of chemistry. The content have the levels of various competition exams.
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Inorganic Chemistry: Principles of structure And Reactivity by James E. Huheey
Summary of Contents [Chapter vise]
Chapter 1. What Is Inorganic Chemistry?
- Inorganic Chemistry, the Beginnings
- Inorganic Chemistry, an Example
- Chemical Structure of Zeolites and Other Chemical System
- Chemical Reactivity
- Conclusion
Chapter 2. The Structure of the Atom
- The Hydrogen Atom
- The Polyelectronic Atom
Chapter 3. Symmetry and Group Theory
- Symmetry Elements and Symmetry Operations
- Point Groups and Molecular Symmetry
- Irreducible Representations and Character Table
- Uses of Point Group Symmetry
- Crystallography
Chapter 4. Bonding Models in Inorganic Chemistry: 1. Ionic Compounds
- The Ionic Bond
- Lattice Energy
- Size Effects
- The Predictive Power of Thermochemical Calculations on Ionic Compounds
- Covalent Character in Predominantly Ionic Bonds
- Conclusion
Chapter 5. Bonding Models in Inorganic Chemistry: 2. The Covalent Bond
- Valence Bond Theory
- Molecular Orbital Theory
- Electronegativity
Chapter 6. The Structure and Reactivity of Molecules
- The Structure of Molecules
- Structure and Hybridization
- Bond Lengths
- Experimental Determination of Molecular Structure
- Some Simple Reactions of Covalently Bonded Molecules
Chapter 7. The Solid State
- The Structures of Complex Solids
- Imperfections in Crystals
- Conductivity in Ionic Solids
- Solids Held Together by Covalent Bonding
- Solid-State Materials with Polar Bonds
Chapter 8. Chemical Forces
- Internuclear Distances and Atomic Radii
- Types of Chemical Forces
- Hydrogen Bonding
- Effects of Chemical Forces
Chapter 9. Acid-Base Chemistry
- Acid-Base Concepts
- Measures of Acid-Base Strength
- Hard and Soft Acid and Bases
Chapter 10. Chemistry in Aqueous and Non-aqueous Solvents
- Water
- Non-aqueous Solvent
- Molten Salts
- Electrode Potentials and Electromotive Forces
Chapter 11. Coordination Chemistry: Bonding, Spectra, and Magnetism
- Bonding in Coordination Compounds
- Valence Bond Theory
- Crystal Field Theory
- Molecular Orbital Theory
- Electronic Spectra of Complexes
- Magnetic Properties of Complexes
Chapter 12. Coordination Chemistry: Structure
- Coordination Number 1
- Coordination Number 2
- Coordination Number 3
- Coordination Number 4
- Coordination Number 5
- Coordination Number 6
- Coordination Number 7
- Coordination Number 8
- Higher Coordination Numbers
- Generalizations about Coordination Numbers
- Linkage Isomerism
- Other Types of Isomerism
- The Chelate Effect
Chapter 13. Coordination Chemistry: Reactions, Kinetics, and Mechanism
- Substitution Reactions in Square Planar complexes
- Thermodynamic and Kinetic Stability
- Kinetics of Octahedral Substitution
- Mechanisms of Redox Reactions
Chapter 14. Some Descriptive Chemistry of the Metals
- General Periodic Trends
- Chemistry of the Various of Oxygen States of Transition Metals
- The Chemistry of Elements Potassium-Zinc: Comparison by Electron Configuration
- The Chemistry of the Heavier Transition Metals
- Oxidation States and EMF's of Groups 1-12
- The Lanthanide and Actinide Elements
- Coordination Chemistry
- The Transactinide Elements
Chapter 15. Organometallic Chemistry
- The 18-electron Rule
- Metal Carbonyl Complexes
- Nitrosyl Complexes
- Dinitrogen Complexes
- Metal Alkyls, Carbenes, Carbynes, and Carbides
- Non-aromatic Alkene and Alkyne Complexes
- Metallocenes
- Reactions of Organometallic Complexes
- Catalysis by Organometallic Compounds
- Stereochemically Nonrigid Molecules
- Conclusion
Chapter 16. Inorganic Chains, Rings, Cages and Clusters
- Chains
- Rings
- Cages
- Boron Cage Compounds
- Metal Clusters
- Conclusion
Chapter 17. The Chemistry of the Halogens and the Noble Gases
- Noble Gas Chemistry
- Halogens in Positive Oxidation States
- Halides
- Pseudohalogens
- Electrochemistry of the Halogens and Pseudohalogens
Chapter 18. Periodicity
- First- and Second-Row Anomalies
- The Use of p Orbital in pi Bonding
- The Use (or Not) of d Orbitals by Non-metals
- Reactivity and d Orbital Participation
- Periodic Anomalies of the Nonmetals and Posttransition Metals
Chapter 19. The Inorganic Chemistry of of Biological Systems
- Energy Source of Life
- Metalloporphyrins and Respiration
- Dioxygen Binding, Transport, and Utilization
- Electron Transfer Respiration and Photosynthesis
- Enzymes
- Nitrogen Fixation
- The Biochemistry of Iron
- Essential and Trace Elements in Biological Systems
- Biochemistry of Nonmetals
- Medical Chemistry
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